Wet h2s damage blistering hicsohicscc creepstress rupture polythionic acid cracking naphthenic acid corrosion ammonium chloride corrosion hcl corrosion oxidation caustic cracking caustic corrosion erosionerosioncorrosion chloride stress corrosion cracking short term overheatingstress rupture 885 embrittlement disimilar metal weld dmw. Two examples of stress corrosion cracking scc in refinery equipment are presented to highlight the lessons learned to prevent recurrence of such failures. Stress corrosion cracking by krittin rattakham youtube. However, to avoid scc in austenitic ss steels, exposure to conducive environment polythionic acid formation in presence of oxygenwaterchlorides along with metal sulfidesh2s to be reduced by adopting. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Among them, the scc due to polythionic acid h 2sxo 6, x 3 6 is one of the most serious corrosion issue affecting equipment for.
The importance of a conjoint action of corrosion and stress as well as the nature of stress is reflected in the definition. Stress corrosion cracking scc can occur in a most metals and alloys due to the combined action of corrosion, tensile stress residual or applied and a susceptible microstructure. Pta scc typically does not occur during normal processing, but rather, after the. Intergranular and transgranular stress corrosion cracking of the aisi 316l stainless steel at polythionic acid environment 8. A fire occurred at the fuel oil desulfurization cracking unit of a refinery 257 hours after startup of the plant, following a turnaround shutdown. Examples of polythionic acid scc pascc in a sensitized austenitic stainless steel and caustic scc in carbon steel equipment are presented. Alloy for resistance to polythionic acid stress corrosion cracking for. Protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during a shutdown of refinery equipment this standard practice provides mitigation methods to protect austenitic stainless steels and other austenitic alloys from pta scc that can occur during a shutdown of refinery equipment.
Stress corrosion cracking by krittin rattakham metal lovers. Both austenitic and straight chromium grades of stainless steels can be attacked by polythionic acid. Protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during shutdown of refinery equipment. If the cracking has been correctly diagnosed as chloride stress corrosion cracking, and the problem is confined to small drain, flush fittings, etc. The mechanism of stress corrosion cracking scc involves a very complicated sequence of corrosion and fracture. Stress corrosion cracking susceptibility of stainless steels. Polythionic acid is formed in the presence of sulfur, moisture and oxygen. The combination of a sensitized microstructure, sulfide scale, moisture, oxygen and residual or applied tensile stress are necessary conditions to produce polythionic acid stress corrosion cracking pta scc. Stress corrosion cracking scc in stainless steels request pdf.
Refer also to nace rp0170, protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during shutdown of refinery equipment. Stress corrosion of austenitic steels is usually transgranular. Stress corrosion cracking scc caused by polythionic acid andor chlorides has occurred in coal liquefaction pilot plants. The austenitic stainless steel tubes in these services can be susceptible to polythionic acid stress corrosion cracking. In each failure analysis case study, the cracking is characterized using various metallurgical laboratory techniques, including metallography and fractography, in.
Abstractlow temperature stress corrosion cracking of sensitized stainless steel, promoted by aqueous solutions of polythionates sxo, and related sulfur compounds. Carbonate cracks are suface breaking flaws that are predominantly intergranular in nature and typically occur in aswelded carbon steel fabrications as a network of very fine, oxidefilled cracks similar in appearance to caustic stress corrosion cracking and amine stress corrosion cracking. Trithionic acid h 2 s 3 o 6, tetrathionic acid h 2 s 4 o 6 are simple examples. It follows the pattern of grains in the individual lattices of the material. This phenomenon is usually an internal problem, occurring on the processexposed side of a piping run, vessel shell, exchanger bundle, heater tube. Based on this analysis the leaks were caused by cracks that initiated on the id surface. Then, the stress corrosion cracking mechanism for various materials in conditions that are susceptible is discussed in detail. Polythionic acid stress corrosion cracking deterioration. What are the industrial practices being followed in refineries to mitigate polythionic acid corrosion in furnaces. Cracking of sensitized stainless steels inspectioneering.
However, to avoid scc in austenitic ss steels, exposure to conducive environment polythionic acid formation in presence of oxygenwater. There are several types of stress corrosion cracking scc, for example, chlorideinduced scc and h 2 sinduced scc. Abstract stress corrosion tests using ubend specimens were carried out in samans solutions containing polythionic acid concentrations from 0. Pdf stress corrosion cracking damages researchgate. Start studying refinery environment assisted cracking.
Stress corrosion cracking occurred at the drain valve connection piping located upstream of an emergency shutoff valve at the outlet of a hydrogen heating furnace, resulting in a hydrogen leak and fire. Standard recommended practice austenitic stainless steels. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Generally, polythionic acid stress corrosion cracking occurs in austenitic. Polythionic stress corrosion cracking of stainless steel tube. Other forms of scc in stainless steels include caustic cracking and polythionic acid scc. Effect of polythionic acid concentration on stress. Polythionic acid stress corrosion cracking pascc occurs in refinery units processing sulfurous streams.
May 27, 2011 other forms of scc in stainless steels include caustic cracking and polythionic acid scc. Among them, the scc due to polythionic acid h 2sxo 6, x 3 6 is one of the most serious corrosion issue affecting equipment for hydrotreater and hydro. Abstract polythionic acid stress corrosion cracking pta scc of conventional austenitic stainless steel is a serious problem in refinery desulfurization units. Polythionic acid stress corrosion cracking pascc is a type of intergranular stress corrosion that affects sensitized stainless steels in refineries processing feedstocks containing sulphur. It is a very severe, rapid form of intergranular scc that attacks sensitized austenitic stainless steels such a weld hazs in type 304. Alloy 625 can play a significant role within the typical refinery by inhibiting naphthenc acd corrosion. Transgranular corrosion is a type of localized corrosion which occurs along cracks or faults across the crystals in metals and alloys. Polythionic acid stress corrosion cracking pascc is a type of intergranular. General and stress corrosion cracking scc behaviors of a nimocr alloy.
However, piehl considered that the corrosive species actually responsible for the intergranular scc was probably sulfurous rather than polythionic acids piehl 1964, which also forms readily during refinery shutdown conditions. Citeseerx document details isaac councill, lee giles, pradeep teregowda. Presence of cr, carbon, exposure temperatures and presence of polythionic acids play an important role in stress corrosion cracking. The stabilized alloys 321 and 347 offer a solution to polythionic acid scc by resisting sensitization during elevated temperature service. Polythionic acid stress corrosion cracking pascc occurs in. Intergranular cracking tendencies of fourteen stainless steels and two highnickel alloys have been evaluated by exposing numerous specimens to polythionic acid and standard acid copper sulfate solutions. Stress corrosion cracking leads to a hydrogen leak and. Standard recommended practice austenitic stainless steels and. The resistance of various commercial alloys to stress corrosion cracking scc in 50% naoh was evaluated at temperatures in the range 284 to 332 c. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment.
However, austenitic stainless steels are susceptible to stress corrosion cracking scc after welding. Further progress is then a process alternating between corrosion and mechanical cracking until the material fails completely. Chemical studies of polythionic acid stresscorrosion cracking. The most common fluid causing intergranular corrosion in hydrocarbon plants is polythionic acid. One of the most important forms of stress corrosion that concerns the nuclear industry is chloride stress corrosion. The stress corrosion cracking sco of sensitized type 304 stainless steel in thiosulfate. Polythionic acid stress corrosion cracking pascc is an affliction of many refineries processing sulfur containing feedstocks, and since that is the norm these days, most refiners reduce their susceptibility to pascc by selecting resistant alloys orby neutralizing exposed surfaces during shutdowns. Anybody aware of any ndt method that can be used to test for the presence of polythionic acid stress corrosion cracking in heatr pipes in a fired heater. Polythionic acid scc has occurred in oil refinery environments where sulfides are common. Nace sp0170 protection of austenitic stainless steels. Polythionic acid is another environment, which causes scc in.
In this chapter, the conditions for the occurrence of scc are first introduced. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. The cracks are intergranular and narrow with no significant branching. The practice is directed toward preventing scc by polythionic acids formed by the reaction of sulfide corrosion products with oxygen. Alloy for resistance to polythionic acid stress corrosion. Polythionic acid stresscorrosion cracking pascc occurs in refinery units processing sulfurous streams. Protection of austenitic stainless steels and other. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be vulnerable under certain conditions. Polythionic acids form from sulfide scales exposed to oxygen and water in the stainless steel that are sensitized which can occur in most stainlesssteel tube materials after exposures to temperatures in excess of 700f to 1500f 371c to 815c during manufacturing, fabrication or in service. Effect of polythionic acid concentration on stress corrosion cracking of sensitized 304 austenitic stainless steel. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Stress corrosion cracking can proceed in one of two ways.
Why does chloride stress corrosion cracking and pascc only. All of the cracks observed were found underneath the coke deposits. Highnickel alloys, such as alloy 600 or, better, commercially pure nickel uns n02201, are used for hot concentrated caustic. Polythionic acid stresscorrosion cracking pascc is caused by sulfur. Stress corrosion cracking issues in syngas plants that may. Effect of polythionic acid concentration on stress corrosion. Ssc is a form of hydrogen stress cracking resulting from absorption of atomic hydrogen that is produced by the sulfide corrosion process on the metal. Stress corrosion cracking scc is the formation and growth of crack through materials subjected to tensile stress and a specific corrosive medium. Resistant to chloride and polythionic acid stress corrosion cracking.
Chloride stress corrosion cracking cl scc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Stress corrosion cracking susceptibility of stainless. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Polythionic acid stress corrosion cracking occurs on sensitized stainless heater tubes in hydroprocessing units. Learn vocabulary, terms, and more with flashcards, games, and other study tools. Polythionic acid is a generic term used to describe acids of the form h 2 s x o 6. Stress corrosion cracking scc may be defined as the delayed failure of alloys by cracking when exposed to certain environments in the presence of a static tensile stress.
Polythionic acid stress corrosion cracking pascc is an affliction of many refineries processing sulfur containing feedstocks, and since that is the norm these days, most refiners reduce their susceptibility to pascc by selecting resistant alloys. Exposure to oxygen and water during turnaround forms polythionic acid and that leads to pta scc on sensitized stainless steel, where soda ash washing, nitrogen purge and pwht is required as a nace countermeasure. Stress corrosion cracking leads to a hydrogen leak and fire. This standard is directed toward preventing stress corrosion cracking scc caused by polythionic acid pta that can be formed by reaction of oxygen and water with sulfide corrosion products i. Ctlpolythionic stress corrosion cracking of stainless. Stress corrosion cracking scc is the formation and growth of crack. Polythionic acid stress corrosion cracking in heater pipes. Stress corrosion cracking can lead to catastrophic brittle failure. It has been shown that, for some materials, fine pitting is needed to start the activity.
Polythionic acids form from sulfide scales exposed to oxygen and water in the stainless steel that are sensitized which can occur in most stainlesssteel tube materials after exposures to temperatures in excess of 700f to. Polythionic acid is an oxoacid which has a straight chain of sulfur atoms and has the chemical formula s n so 3 h 2 n 2. Refinery environment assisted cracking flashcards quizlet. These characteristics are consistent with stress corrosion cracking due to polythionic acids. Under conditions of stress, intergranular cracks form. This recommended practice provides methods to protect austenitic stainless steel from polythionic acid stress corrosion cracking scc found to occur during downtimes and contiguous shutdown and startup periods. The most common fluid that causes inter granular stress corrosion cracking igscc in petrochemical plants and refineries is polythionic acid. Effect of carbon content on polythionic acid stress corrosion. Subsequently, this particular form of intergranular scc was called polythionic acid stress corrosion cracking pascc. Samans, stress corrosion cracking susceptibility of stainless steels and nickelbase alloys in polythionic acids and acid copper sulfate solution, corrosion. What are the industrial practices being followed in. Siconversionunits inviewofpresentacceptedpracticeinthistechnologicalarea,u. In each failure analysis case study, the cracking is characterized using various metallurgical laboratory techniques, including metallography and fractography, in order to identify the mode of failure. This standard recommended practice provides methods to protect austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking pta scc occurring during downtimes and contiguous shutdown and startup periods.
Alloy performance guide rolled alloys rolled alloys 2 rolled alloys strength of a company lies in the strength of its people. This standard practice provides mitigation methods to protect austenitic stainless steels and other austenitic alloys from polythionic acid pta stress corrosion cracking scc that can occur during a shutdown of refinery equipment. Methods to protect austenitic stainless steel from polythionic acid stress corrosion cracking scc found to occur during downtimes and contiguous shutdown and startup periods. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. Chloride stress corrosion cracking inspectioneering. However, stress corrosion cracking continues to be a problem in aging plants and must be considered when completing a riskbased inspection program or setting integrity operating windows. Sulfur can come from feed stock, additives or fuels. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. Scc of sensitized austenitic stainless steel has been reported in borate. The sensitization curves for solutionannealed wrought stainless steels, which had been held for varying times at temperatures. A shutdown includes the actual down time period and the contiguous periods required to shut down and start up the equipment. Caustic may crack carbon as well as stainless steel. Are there any methods that can be used to give a 100% picture of the status of the pipes whilst they are mounted in the heater.
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